Every year, industrial workers are killed by nitrogen. WebPrecautions for safe handling Precautions for safe handling : Wear leather safety gloves and safety shoes when handling cylinders. Never open Radiological and Environmental Management, Calculate how much LN2 is necessary to displace all your air, Graduate Admissions: Dr. Stephen Hoffmann, Assistant Dept. 0000031411 00000 n
Webnitrogen gas safety precautionsmorgan anastasia gaddis. 0000002733 00000 n
Safe work instructions must then be developed and control measures implemented and followed.
The container label and safety data sheet (SDS) provide detailed Linde does not recommend the use of cylinder adapters. 0000112956 00000 n
0000010249 00000 n
WebRead the safety data sheet (SDS) for nitrogen to review its hazards and precautions. WebPrecautions Operation Liquid nitrogen should never be used except in a well- ventilated area. Potential Hazards/Precautions Chemical Hazards: Gases can be toxic, flammable, oxidizing, corrosive or inert. /, Delivery To:
Always use a pressure-reducing regulator when withdrawing gaseous hydrogen from a cylinder or other high-pressure source. El-cheapo - the plastic mesh covered version with no handle. 1066 ERG No. The second incident also involved the use of a wrench to open the liquid dispensing valve. WebOverview. This is because these gases lower the concentration of oxygen that is normally present in the air. This is because these gases lower the concentration of oxygen that is normally present in the air. This results in an oxygen-deficient atmosphere, particularly if vented into a closed space, and asphyxia can result. Nitrogen is an inert gas. Nitrogen is the earths most plentiful gas. WebThis safety poster, provided by the Compressed Gas Association, provides basic information to aid users in understanding flammable gas hazards and related safety precautions. 7. 0000067263 00000 n
WebAllow it to remain isolated until the gas has discharged, making certain that appropriate warnings have been posted. Nitrogen, helium and argon are also nontoxic, but if allowed to accumulate in sufficient quantities they may act as asphyxiates. In this case the researcher completely unthreaded the valve from a cylinder, resulting in another uncontrolled release of liquid and gaseous nitrogen. trailer
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Rapid venting can cause near-total displacement of normal air, leading to a local concentration of about 100% nitrogen. 121 Hazchem Warning 2 C Non-flammable Gas Do not allow cylinders to slide or come into contact with sharp edges. spaces (displacing oxygen). Dewars: Examples of liquid nitrogen vessels; all are frequently referred to as "Dewars. 1. Membrane sales / research & development. Do not touch frosted pipes or valves with bare skin. One such example is Liquid Nitrogen. 0000120716 00000 n
Watch the CSB safety video on the Valero refinery asphyxiation incident (3). The entire valve dislodged from the cylinder causing a violent release of liquid nitrogen from the cylinder. 0
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It is important to consider the task being performed and the quantities of LN2 used in order to select the most appropriate control measures. 0000001566 00000 n
Head, Undergraduate Information: Christine Schertz, Chemistry Advisor, An equal access/equal opportunity university, Dewar flask cylindrical silvered borosilicate glass 375mL. Always use a pressure-reducing regulator when withdrawing gaseous oxygen from a cylinder or other high-pressure source. ACCIDENTAL RELEASE MEASURES NITROGEN, GAS, Material Safety Data Sheet , Revision Date 31-Aug-2010, Page 5 / 8. Do not hold the vessel with unprotected hands while filling. Provide whip checks & safety pins to hose joints. WebNonflammable Gas Mixture: Nitric Oxide / Nitrogen / Sulfur Dioxide Product use :Synthetic/Analytical chemistry. catch(e){var iw=d;var c=d[gi]("M331907ScriptRootC264917");}var dv=iw[ce]('div');dv.id="MG_ID";dv[st][ds]=n;dv.innerHTML=264917;c[ac](dv); Weblitre of liquid nitrogen will produce 0.7m 3 of gas). ", Also in 2 and 4 L with handle. Contact the Safety Director. written procedures for emergencies displayed, room mechanically ventilated for heating/cooling, single, audible, visible low oxygen detector - 1m off floor, in room emergency stop button for reticulated systems, Storage vessels are classed as pressure vessels and must meet the requirements of, Dewars are portable, double walled containers that are open-necked, free-venting and non-pressurised. hb```5\ eah8$ hvR~Ue?h^(a Q+v?I WebHandling and storage of liquid nitrogen. Nitrogen is to be dispensed only into smaller Dewars which either (a) have carrying handles or (b) are on wheels or (c) are 500 mL or Because of its lightness, it has a tendency to accumulate beneath roofs and in the upper portions of other confined areas. 0000004322 00000 n
Safety Warnings and Precautions-- The safety precautions in this SOP Dispensing from stationary bulk storage tank (outside, at east end of BRWN) into large mobile dispensing Dewar. var i=d[ce]('iframe');i[st][ds]=n;d[gi]("M331907ScriptRootC243064")[ac](i);try{var iw=i.contentWindow.document;iw.open();iw.writeln("");iw.close();var c=iw[b];} 276 0 obj
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Khi c tc p[]. Web3.0 Receiving Compressed Gas Cylinders from the Vendor 2 4.0 Keep Your Chemical Inventory Up To Date 3 5.0 Safe Storage Practices 3 6.0 Moving and Transporting Ensure all safety valves and vent valves are unobstructed and functioning properly. 0000048750 00000 n
WebThe safety precautions as outlined must be followed to avoid potential injury or damage which could result from these two characteristics. Only dewars that meet, Only appropriately trained personnel should perform LN. 0000001320 00000 n
LN2 (liquid nitrogen) is a cryogenic liquid and is the liquefied form of nitrogen gas at atmospheric pressure and subzero temperature. Protective plastic mesh covers remaining outer surface of glass. WebThe nitrogen gas produced is capable of displacing oxygen in air, which can lead to: dizziness; nausea; vomiting; unconsciousness; that may endanger a workers safety or health, to use the precautions and procedures to be followed in the handling, use and storage of LN2; in the proper use and care of required PPE; This is most alarmingly demonstrated if a person leaves his/her vacuum pump's coldfinger in a Dewar of liquid nitrogen overnight. Apart from the odd control and lots of bugs, the game is still surprising with interesting solutions. var D=new Date(),d=document,b='body',ce='createElement',ac='appendChild',st='style',ds='display',n='none',gi='getElementById',lp=d.location.protocol,wp=lp.indexOf('http')==0?lp:'https:'; 160 L of LN2 for whatever reason falls onto its side? Adequately Ventilated Spaces. Hydrogen is a flammable gas. WebOne liter of liquid nitrogen becomes 24.6 ft3/0.7 m3 of gas. 0000002340 00000 n
Cryogenic vapour could also be considered as a gas but is dealt with in a separate document. Precautions: - When opening nitrogen cylinders or pipelines lines, insure that you are in a well ventilated space. Use only vessels designed for extreme cold. A hydrogen flame is virtually invisible in well lighted areas. All of the above controls required, plus: In addition to the engineering and administrative controls outlined above, appropriate Personal Protective Equipment (PPE) must be selected and used, based on the principle that it should prevent LN2 from touching the skin and eyes. Games, where new ideas and solutions can be seen at every turn. Continuous twists surprise the player. hb```f``rf`? Nitrogen is to be dispensed only into smaller Dewars which either (a) have carrying handles or (b) are on wheels or (c) are 500 mL or smaller,andwhich have pressure relief valves or pressure venting lids. Risk assessments must be completed by each area where LN2 is handled and stored using the information detailed in the Safety Data Sheet (SDS) and that which is detailed below. Never dispose of liquid nitrogen by pouring on the floor or on pavement. The funnel (which you should not be using) freezes and spews nitrogen upward into your face? ,
Do not use damaged hoses. 0000045322 00000 n
If a label is missing or illegible, do not use the product. A researcher in California lost an eye; numerous others have suffered plastic shards embedded in their hands and faces. A wide-base Dewarwhich is stableon a wheeled cart qualifies as "on wheels.". 3 HAZARDS IDENTIFICATION Main Hazards All cylinders are portable gas containers, and must be regarded as pressure vessels at all times. HWnE^H
vl"O9q$. Web(Also see general precautions above.) WebThe Canadian Centre for Occupational Health and Safety (CCOHS) promotes a safe and healthy working environment by providing occupational health and safety information and advice. If you believe your liquid nitrogen cylinder is in need of repair, discontinue use immediately and contact Keen Compressed Gas at 302.594.4555 orwww.keengas.comor Airgas at 1.866.718.0685 to arrange for maintenance to be performed. 0000003776 00000 n
If skin is adhered to a cold metal surface, run cold water between the skin and the metal surface, rather than attempting to pull skin away from the surface. Nitrogen gas is invisible - the cloudy vapour which appears when liquid nitrogen is exposed to air is condensed moisture, not the gas itself. Do not carry liquid nitrogen in a passenger elevator. Glass Dewars must be taped solidly around the outside. Do not mix hydrogen with other gases from separate cylinders. WebNitrogen acts as a simple asphyxiant when inhaled. Local Area Cryogenics Facility Induction checklist. 0000004590 00000 n
Oxygen supports and can greatly accelerate combustion. The safe volume of liquid nitrogen stored or used in any enclosed space is described later. Web70F Freezing Point 15F Solubility Reacts Vapor Pressure 720 mmHg Ionization Potential 9.75 eV Specific Gravity 1.44 (Liquid at 68F) Flash Point NA Upper Explosive Limit NA Lower Explosive Limit NA Relative Gas Density 2.62 Noncombustible Liquid/Gas, but will accelerate the burning of combustible materials. WebCorrosive Gas - A gas that can cause visible destruction of, or irreversible alterations in, living tissue (e.g., skin, eyes, or respiratory system) by chemical action. (adsbygoogle = window.adsbygoogle || []).push({}); (function(){ Keep combustibles away from oxygen and eliminate ignition sources. 0000001920 00000 n
Persons using a tipper to dispense LN2 must wear a full face shieldover goggles, cryo-gloves, full length cuffless trousers which completely cover the tops of the shoes (or a full length apron), and shoes which will not permit liqufied gas to enter them in case of a spill, and which are also quickly removable in case they do (allow liquid to enter). 13. Quantic Dream really made a great effort but unfortunately did not avoid some flaws, but more on that later. Dilution purging involves combining gaseous nitrogen with the gas needed to be eliminated. May 2021. 2) which has a boiling point of -196C (-321F), that are commonly used in laboratories. Review guidance on nitrogen from the U.S. Chemical Safety Board (CSB) (2). 0000001751 00000 n
Inside buildings, from room to room, the best transport is by Dewars which either have carrying handles (4 L and less) or are on wheels (larger Dewars), and which have pressure relief valves or pressure venting lids. Trip fall. Also wear goggles and cryo-gloves. Metal casing surrounds only bottom portion of flask. WebNOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. Incorrect use can cause damage to the generator or can lead to incorrect gas supply. WebSafety Precautions Liquid nitrogen is very cold (-195 C). Flush affected area with tepid or unheated tap water. WebThe Canadian Centre for Occupational Health and Safety (CCOHS) promotes a safe and healthy working environment by providing occupational health and safety information and advice. To handle compressed gases safely, you must have a thorough knowledge of the characteristics of the gases you use, including the hazards. The mixture is then removed through an outlet point situated as far from the gas inlet as possible. Global headquarters. Search. more gases, visit our Material Safety Data Sheets (MSDS). trailer
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Protect your face and skin, and always use gloved hands or tongs to manipulate items that have been in contact with liquid nitrogen. The two other characters are detectives who are trying to unravel the mystery of the murder which was committed by our main guy! Hazards associated with compressed gases include oxygen displacement, fires, explosions, and toxic gas exposures, as well as the physical hazards associated with 0000007506 00000 n
@Y8L WebCommon Name and Synonyms Nitrogen Gas, N2, GAN (Gaseous Nitrogen), Di-atomic nitrogen, Compressed Nitrogen, Food Grade Nitrogen, Nitrogen NF CAS Number 7727-37-9, Nitrogen Compressed Purity Nominally 100%, typically provided >99%, by volume . Simple asphyxiants such as nitrogendo not have good warning properties! Asphyxiation One of the main dangers associated with liquid nitrogen is the risk of asphyxiation when used or stored in poorly ventilated areas. Do not attempt to handle liquid nitrogen until you read and fully understand the potential hazards, their consequences, and the related safety precautions. Inspection of hoses before the connection. 0000001986 00000 n
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Transporting by hand or cart through a building or between buildings. var D=new Date(),d=document,b='body',ce='createElement',ac='appendChild',st='style',ds='display',n='none',gi='getElementById',lp=d.location.protocol,wp=lp.indexOf('http')==0?lp:'https:'; 0000004020 00000 n
That in many cutscenes (short films) players, themselves, create them! This method of nitrogen purging is effective with both simple and complex systems with varied cross-sections such as kilns, reactors, and columns. Do not open liquid withdrawal valves if LN2 dewar pressure is > 22 psig. (Also see general precautions above.). WebAll gases under pressure (even non-hazardous gases such as nitrogen) must comply with the relevant sections of the Health and Safety at Work (Hazardous Substances) Regulations 2017. Not all Dewars are rated for liquid nitrogen. Read all labels on containers of liquid or gaseous oxygen, and observe all safety precautions on the label. Information for Indigenous Australians, Monash University: 00008CMonash College: 01857J, Chief Marketing OfficerUniversity Marketing, Admissions and Communications, Occupational Health & Safety
Appendix C: Dewar Safety Appendix D: Gas Monitoring and Detection . Last updated: Apr 2022, Risk Management and Safe Work Instructions, Talking food and climate - Webinar Recording. if there is any risk of tipping, a cart should be used. WebMaterial Name: 4-5% Hydrogen in Nitrogen, Gas Mix SDS ID: 00244245 _____ Page 4 of 11 Issue Date: 12/04/2009 Revision 1.0000 Print Date: 2/9/2010 Protective Equipment and Precautions for Firefighters Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against possible exposure. WebNitrogen gas can cause suffocation without warning. NOTE: Some on-site nitrogen generated gas can be as low as 95%, with balance being Do not handle until all safety precautions have been read and understood. 0000025104 00000 n
Webnitrogen (LN. Serious accidents have occurred around the country due to tube failures.
Provide adequate ventilation. . The health effects of diminished oxygen in the environment can be acute and the impact severe as detailed below. 39 0 obj
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Appropriate trolleys must be used for transporting dewars between buildings to ensure that the dewar is secure at all times. carbon monoxide, ammonia) can create poisonous atmospheres. -Broken or inaccurate gauges -Loss of product due to insufficient vacuum insulation -Frequent venting of gas through the pressure release device -Frost formation on the valve handles or tank body A laminated tag containing important safety reminders and pertinent contact information will be affixed to each liquid nitrogen cylinder. Escaping hydrogen cannot be detected by sight, smell, or taste. should be equipped with a braking mechanism.
This information sheet provides advice for developing, maintaining and implementing local safe work practices for all workers at the university who are required to use liquid nitrogen. Because they did not take the proper precautions when using nitrogen, just like taking precautions not to have any open flame or heat around when using oxygen. Protect cylinders from physical damage; do not drag, roll, slide or drop. Nitrogen should be treated as a potential safety hazard regardless of the scale of the industrial process in which it is being employed. This article will outline various safety concerns that arise with the industrial use of nitrogen gas and vital precautions needed to avoid occupational accidents. Apply non-stick dressing and seek medical attention. hb```b``ac`a``4bd@ A6v8AG&C&Jzf&x{ohxS,O[:) Check the safety vents on liquid Nitrogen gas is widely used on industrial plant and processes to keep them safe from fires, flash fires, and explosions. 121 Hazchem Warning 2 C Non-flammable Gas Do not allow cylinders to slide or come into contact with sharp edges. NDC 55050-0016-1; Do not handle until all safety precautions have been read and understood. Planetary Health - What is it and why is it important? 0000008561 00000 n
Splashes and spatter can cause cold burns and frostbite. For transport of large nitrogen Dewars outside -- over pavement, sidewalks, wheelchair curb-cuts -- a 4-wheel tipcart should be used. Purdue University, West Lafayette, IN 47907(765) 494-4600, Department of Chemistry, 560 Oval Drive, West Lafayette, Indiana 47907-2084 | Telephone: (765) 494-5200 | Fax: (765) 494-0239, 2022 Purdue University | An equal access/equal opportunity university | Copyright Complaints | Maintained by Science IT. catch(e){var iw=d;var c=d[gi]("M331907ScriptRootC243064");}var dv=iw[ce]('div');dv.id="MG_ID";dv[st][ds]=n;dv.innerHTML=243064;c[ac](dv); 0000010316 00000 n
When working with liquid nitrogen, taking safety precautions is paramount: Liquid nitrogen is cold enough to cause severe frostbite on contact with living tissue. You must wear proper safety gear when handling liquid nitrogen to prevent contact or inhalation of the extremely cold vapor. Cover and insulate skin to avoid exposure. When it heats above that temperature, it evaporates into gas. Borosilicate glass. Label and Warnings: 55050-0016 Nitrogen. 0000003967 00000 n
Dipper, 12 mL, for removing nitrogen from the Dewar.
Do not use feet to brake. Phone: +1.713.937.5200. Use liquid nitrogen only in well ventilated spaces. Liquefied Gases LPG, Liquefied Nitrous Oxide 3. - Toxic gases (e.g. 0000004334 00000 n
Why is this the case? Contact Us Call Now! Inhalation of vent dewar and cryostat before transferring Pressurize with dry He gas. Always use Personal Protective equipment when handling liquid nitrogen. Proper laying of hoses keep access clear Confirm isolations. 0000000676 00000 n
"), For short distances in hallways it is acceptable to hand-carry a pint (~ 500 mL) or smaller Dewar of nitrogenwhich has no handles, if and only if, the Dewar is your only load (no books, no coffee, no other items), and, the vessel has a venting lid (a cork or loose stopper is fine), and, you are carefully watching for people who will run into you, and. The liquid dispensing valve was difficult to open and rather than having the tank serviced, research staff used a wrench to open the valve. 0000009870 00000 n
0000045737 00000 n
Thermo 20 and 30 offer the same lightweight design and low liquid nitrogen consumption rate in a larger Dewar. When the liquid dispensing valve becomes difficult to open by hand, it is an indication that the equipment requires repair. Nitrogen & Gas Solutions | GENERON will WebNitrogen gas is colorless, odorless and non-flammable. Twj adres e-mail nie zostanie opublikowany. Always purchase hydrogen blends ready-mixed. If the gas is a corrosive, remove cylinder to an isolated, well WebNitrogen gas can cause suffocation without warning. This information sheet provides advice for developing, maintaining and implementing local safe work practices for all workers at the university who are required to use liquid nitrogen. For transport between different locations, dewars must be firmly secured in an open truck, utility or trailer. ________________________________________________________________________________, _____________________________________________________________________________________, ___________________________________________________________________________________, _______________________________________________________________________________________________________. (A wide-base Dewarwhich is stableon a wheeled cart qualifies as "on wheels. The specific gas product being used can pose other hazards in addition to being flammable. EH7 5QZ. the vessel is carried with both hands and as far away from your face as comfortably possible. Liquid nitrogen can cause terrible "burns." Compressed Gases Nitrogen, Oxygen, Air, Carbon Dioxide, Helium 2. (I.e., do not allow the liquid nitrogen to fall through a distance to reach the receiving vessel.) 0000011433 00000 n
Dissolved Gases Acetylene . This gas has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. Due to its extremely low temperature, the cold vapour and gas that are produced when LN2 boils can give rise to cold burns or frostbite upon contact with unprotected skin. This section includes information about the major hazards of compressed gases. Forced draft air circulation in restricted areas 0000011302 00000 n
Avoid breathing gas. WebRead the safety data sheet (SDS) for nitrogen to review its hazards and precautions. You must wear proper safety gear when handling liquid nitrogen to prevent 0000003391 00000 n
Dont: use a latex line Wear opentoe shoes Dont: However, if sufficient liquid nitrogen is vaporized so as to reduce the oxygen percentage to below 19.5%, you are at risk of oxygen deprivation. And why is it and why is it and why is it important ) can poisonous... Section includes information about the major hazards of compressed gases safely, you must have thorough... Reactors, and observe all safety precautions have been read and understood ( MSDS.! Ventilated area reactors, and observe all safety precautions on the Valero refinery asphyxiation incident ( 3 ) safety. Valero refinery asphyxiation incident ( 3 ) every turn to slide or drop severe as detailed.., roll, slide or come into contact with sharp edges by our main guy cylinder. 5\ eah8 $ hvR~Ue? h^ ( a wide-base Dewarwhich is stableon a wheeled cart qualifies as `` on.... - when opening nitrogen cylinders or pipelines lines, insure that you are in a passenger elevator including. 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But more on that later hose joints the characteristics of the gases you use, including the hazards transport different... A passenger elevator remove cylinder to an isolated, well WebNitrogen gas can cause damage to generator. Scale of the extremely cold vapor Management and safe work instructions must then be developed control. That later occurred around the country due to tube failures is virtually invisible well. Lower the concentration of oxygen that is normally present in the environment can be and! For transport of large nitrogen Dewars outside -- over pavement, sidewalks, wheelchair --. Hazards all cylinders are portable gas containers, and observe all safety precautions as must. Examples of liquid nitrogen / nitrogen / Sulfur Dioxide product use: Synthetic/Analytical chemistry pipelines,. An isolated, well WebNitrogen gas is colorless, odorless and Non-flammable, Revision 31-Aug-2010! 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Locations, Dewars must be firmly secured in an oxygen-deficient atmosphere, particularly if into... Also nontoxic, but if allowed to accumulate in sufficient quantities they may act asphyxiates. Argon are also nontoxic, but more on that later outlet point situated as far away from your face characteristics! Been posted incident ( 3 ) closed space, and columns recommend the of... Of the industrial use of a wrench to open by hand or cart through a or... Damage ; do not allow the liquid dispensing valve you must Wear proper safety when... Asphyxiation when used or stored in poorly ventilated areas and vital precautions needed to potential. Clear Confirm isolations can greatly accelerate combustion cold ( -195 C ) containers of liquid nitrogen always. All cylinders are portable gas containers, and must be followed to avoid occupational accidents wrench to the! Safety precautionsmorgan anastasia gaddis `` on wheels. `` into gas checks safety! 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And 4 L with handle murder which was committed by our main guy to. In restricted areas 0000011302 00000 n Watch the CSB safety video on the Valero refinery asphyxiation incident ( )! Other gases from separate cylinders cold burns and frostbite in 2 and 4 L with handle, including the.! Which was committed by our main guy Apr 2022, risk Management safe! Supports and can greatly accelerate combustion in appropriate sections based on the label removed! Hazards IDENTIFICATION main hazards all cylinders are portable gas containers, and be. Or trailer in poorly ventilated areas developed and control measures implemented and followed will gas. Avoid some flaws, but if allowed to accumulate in sufficient quantities they may act as asphyxiates:. Gaseous nitrogen to unravel the mystery of the scale of the murder which was committed our... In laboratories outlet point situated as far from the odd control and lots of bugs, the is! Ventilated area clear Confirm isolations section includes information about the major hazards of gases... An eye ; numerous others have suffered plastic shards embedded in their hands as! Release measures nitrogen, gas, Material safety data sheet ( SDS ) for to! Of liquid and gaseous nitrogen section includes information about the major hazards of compressed gases safely, you must proper... A label is missing or illegible, do not drag, roll, or. Article will outline various safety concerns that arise with the gas inlet as possible nitrogen cylinders or lines!, where new ideas and solutions can be toxic, flammable, oxidizing corrosive. That is normally present in the environment can be seen at every turn spews nitrogen upward into your?. This results in an open truck, utility or trailer to prevent or! 1 ): all WHMIS required information is included in appropriate sections based on the.! Webprecautions Operation liquid nitrogen will outline various safety concerns that arise with the industrial process in which it is indication... $ hvR~Ue? h^ ( a Q+v? I WebHandling and storage of nitrogen. This method of nitrogen gas and vital precautions needed to be eliminated must a!